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San Diego State University

Chemistry & Biochemistry

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Douglas B. Grotjahn

Professor

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Douglas B. Grotjahn: Full Publication List

  1. Sattler, Daniel J.; Bailey, Jake B.; Grotjahn, Douglas B.; "Synthesis and crystal structure of an iridium complex containing the novel electron-poor hybrid monoanionic ligand Ph2PCF2PO2(OiPr)" Polyhedron, 2022, 228, . DOI: 10.1016/j.poly.2022.116162
  2. Ibanez, Miguel; Breyer, Colton James; Grotjahn, Douglas B.; Smith, Diane Kimball; "Further studies on the effects of electron-donating and -withdrawing groups on water oxidation catalysts with phenathrolinesulfonate and terpyridine ligands on ruthenium" Polyhedron, 2022, 228, . DOI: 10.1016/j.poly.2022.116162
  3. Kerkhof, Jake Tyler; James Breyer, Colton; Smith, Diane Kimball; Elliott, Gregory Ian; Grotjahn, Douglas B.; "Novel water oxidation catalysts bearing sulfonate coordinating groups" Polyhedron, 2022, 228, . DOI: 10.1016/j.poly.2022.116162
  4. Gojiashvili, Elguja; Fishler, Benjamin; Alimbarashvili, Davit; Grotjahn, Douglas B.; "Bifunctional phosphines bearing oxygenated substituents, and their metal complexes" Polyhedron, 2022, 228, . DOI: 10.1016/j.poly.2022.116162
  5. Breyer, Colton James; Nash, Aaron Gabriel; Chatfield, Dale; Smith, Diane K.; Pullman, David Paul; Grotjahn, Douglas B.; "Instrumentation for the quantitative analysis of electrochemical water oxidation catalyst performance as well as stability" Polyhedron, 2022, 228, . DOI: 10.1016/j.poly.2022.116162
  6. Nash, Aaron G.; Breyer, Colton J.; Vincenzini, Brett D.; Elliott, Gregory I.; Niklas, Jens; Poluektov, Oleg G.; Rheingold, Arnold L.; Smith, Diane K.; Musaev, Djamaladdin G.; Grotjahn, Douglas B.; "An Active-Site Sulfonate Group Creates a Fast Water Oxidation Electrocatalyst That Exhibits High Activity in Acid" Angew. Chem., Int. Ed., 2021, 60, 1540-1545. DOI: 10.1002/anie.202008896
  7. Sattler, Daniel; Rheingold, Arnold L.; Grotjahn, Douglas B.; "Electron-poor ligands: Synthesis and catalytic application" Angew. Chem., Int. Ed., 2021, 60, 1540-1545. DOI: 10.1002/anie.202008896
  8. Ibanez, Miguel; Breyer, Colton; Kanova, Nilay; Grotjahn, Douglas B.; "Effects of electron-donating and -withdrawing groups on water oxidation catalysts with phenathrolinesulfonate and terpyridine ligands on ruthenium" Angew. Chem., Int. Ed., 2021, 60, 1540-1545. DOI: 10.1002/anie.202008896
  9. Saeedifard, Farzaneh; Breyer, Colton; Cao, Thomas Chi; Kerkhof, Jake; Smith, Diane; Cooksy, Andrew L.; Rheingold, Arnold L.; Moore, Curtis D.; Grotjahn, Douglas B.; "Increasing ligand denticity for water oxidation catalysts using PV as connecting element" Angew. Chem., Int. Ed., 2021, 60, 1540-1545. DOI: 10.1002/anie.202008896
  10. Cao, Thomas C.; Cooksy, Andrew L.; Grotjahn, Douglas B.; "Origins of High Kinetic (E)-Selectivity in Alkene Isomerization by a CpRu(PN) Catalyst: a Combined Experimental and Computational Approach" ACS Catal., 2020, 10, 15250-15258. DOI: 10.1021/acscatal.0c03497
  11. Grotjahn, Douglas B.; "Looking to the oxygen evolving complex of PS II: Bifunctional catalysts for water oxidation" ACS Catal., 2020, 10, 15250-15258. DOI: 10.1021/acscatal.0c03497
  12. Paulson, Erik R.; Moore, Curtis E.; Rheingold, Arnold L.; Pullman, David P.; Sindewald, Ryan W.; Cooksy, Andrew L.; Grotjahn, Douglas B.; "Dynamic π-Bonding of Imidazolyl Substituent in a Formally 16-Electron Cp*Ru(κ2-P,N)+ Catalyst Allows Dramatic Rate Increases in (E)-Selective Monoisomerization of Alkenes" ACS Catal., 2019, 9, 7217-7231. DOI: 10.1021/acscatal.8b04345
  13. Yazdani, Sima; Silva, Braden E.; Cao, Thomas C.; Rheingold, Arnold L.; Grotjahn, Douglas B.; "X-ray crystallography and electrochemistry reveal electronic and steric effects of phosphine and phosphite ligands in complexes RuII(κ4-bda)(PR3)2 and RuII(κ3-bda)(PR3)3 (bda = 2,2'-bipyridine-6,6'-dicarboxylato)" Polyhedron, 2019, 161, 63-70. DOI: 10.1016/j.poly.2018.12.033
  14. Kamdar, Jayneil M.; Grotjahn, Douglas B.; "An overview of significant achievements in ruthenium-based molecular water oxidation catalysis" Molecules, 2019, 24, 63-70. DOI: 10.3390/molecules24030494
  15. Paulson, Erik R.; Delgado, Esteban; Cooksy, Andrew L.; Grotjahn, Douglas B.; "Catalyst versus Substrate Control of Forming (E)-2-Alkenes from 1-Alkenes Using Bifunctional Ruthenium Catalysts" Org. Process Res. Dev., 2018, 22, 1672-1682. DOI: 10.1021/acs.oprd.8b00315
  16. Grotjahn, Douglas B.; Martin, Jessica K.; Tom, Taylon N.; Rheingold, Arnold L.; "Cationic protic imidazolylidene NHC complexes of Cp*IrCl+ and Cp*RhCl+ with a pyridyl tether formed at ambient temperature" Inorganics, 2018, 6, 1672-1682. DOI: 10.3390/inorganics6010027
  17. Barmare, Farhana; Abadjian, Marie-Caline Z.; Wiener, Erik C.; Grotjahn, Douglas B.; "Azide Tripodal Dendrons from Behera's Amine and Their Clicked Dendrimers" J. Org. Chem., 2016, 81, 6779-6782. DOI: 10.1021/acs.joc.6b00859
  18. Marelius, David C.; Moore, Curtis E.; Rheingold, Arnold L.; Grotjahn, Douglas B.; "Reactivity studies of pincer bis-protic N-heterocyclic carbene complexes of platinum and palladium under basic conditions" Beilstein J. Org. Chem., 2016, 12, 1334-1339. DOI: 10.3762/bjoc.12.126
  19. Kamdar, Jayneil M.; Marelius, David C.; Moore, Curtis E.; Rheingold, Arnold L.; Smith, Diane K.; Grotjahn, Douglas B.; "Ruthenium Complexes of 2,2'-Bipyridine-6,6'-diphosphonate Ligands for Water Oxidation" ChemCatChem, 2016, 8, 3045-3049. DOI: 10.1002/cctc.201600359
  20. Larsen, Casey R.; Paulson, Erik R.; Erdogan, Gulin; Grotjahn, Douglas B.; "A Facile, Convenient, and Green Route to (E)-Propenylbenzene Flavors and Fragrances by Alkene Isomerization" Synlett, 2015, 26, 2462-2466. DOI: 10.1055/s-0035-1560205
  21. Marelius, David C.; Darrow, Evan H.; Moore, Curtis E.; Golen, James A.; Rheingold, Arnold L.; Grotjahn, Douglas B.; "Hydrogen-Bonding Pincer Complexes with Two Protic N-Heterocyclic Carbenes from Direct Metalation of a 1,8-Bis(imidazol-1-yl)carbazole by Platinum, Palladium, and Nickel" Chem. - Eur. J., 2015, 21, 10988-10992. DOI: 10.1002/chem.201501945
  22. Grotjahn, Douglas B.; Larsen, Casey R.; Erdogan, Gulin; "Bifunctional Catalyst Control of Alkene Isomerization" Top. Catal., 2014, 57, 1483-1489. DOI: 10.1007/s11244-014-0322-4
  23. Grotjahn, Douglas B.; "Bifunctional catalysts for hydrogen and oxygen chemistry" Prepr. - Am. Chem. Soc., Div. Energy Fuels, 2014, 59, 1483-1489. DOI: 10.1007/s11244-014-0322-4
  24. Erdogan, Gulin; Grotjahn, Douglas B.; "Supported Imidazolylphosphine Catalysts for Highly (E)-Selective Alkene Isomerization" Org. Lett., 2014, 16, 2818-2821. DOI: 10.1021/ol500327k
  25. Larsen, Casey R.; Erdogan, Gulin; Grotjahn, Douglas B.; "General Catalyst Control of the Monoisomerization of 1-Alkenes to trans-2-Alkenes" J. Am. Chem. Soc., 2014, 136, 1226-1229. DOI: 10.1021/ja411438d
  26. Marelius, David C.; Bhagan, Salome; Charboneau, David J.; Schroeder, Kristine M.; Kamdar, Jayneil M.; McGettigan, Amanda R.; Freeman, Benjamin J.; Moore, Curtis E.; Rheingold, Arnold L.; Cooksy, Andrew L.; Smith, Diane K.; Paul, Jared J.; Papish, Elizabeth T.; Grotjahn, Douglas B.; "How Do Proximal Hydroxy or Methoxy Groups on the Bidentate Ligand Affect [(2,2';6',2"-Terpyridine)Ru(N,N)X] Water-Oxidation Catalysts? Synthesis, Characterization, and Reactivity at Acidic and Near-Neutral pH" Eur. J. Inorg. Chem., 2014, 2014, 676-689. DOI: 10.1002/ejic.201300826
  27. Arita, Amy J.; Cantada, Janet; Grotjahn, Douglas B.; Cooksy, Andrew L.; "Computational Study of the Extensive Role of Heterocyclic Ligands in Acetylene Hydration by a Bifunctional Organometallic Catalyst" Organometallics, 2013, 32, 6867-6870. DOI: 10.1021/om400445n
  28. Specht, Zephen G.; Grotjahn, Douglas B.; Moore, Curtis E.; Rheingold, Arnold L.; "Effects of Hindrance in N-Pyridyl Imidazolylidenes Coordinated to Iridium on Structure and Catalysis" Organometallics, 2013, 32, 6400-6409. DOI: 10.1021/om400758b
  29. Grotjahn, Douglas B.; Marelius, David C.; Kamdar, Jayneil M.; Brown, Derek B.; Martin, Jessica K.; Abadjian, Marie-Caline; Tran, Hai N.; Kalyuzhny, Gregory; Vecchio, Kenneth S.; Specht, Zephen G.; Uteuliyev, Maulen M.; Cao, Qinli; "Behavior of molecular organometallic and inorganic catalysts during water oxidation" Prepr. - Am. Chem. Soc., Div. Energy Fuels, 2013, 58, 6400-6409. DOI: 10.1021/om400758b
  30. Larsen, Casey R.; Grotjahn, Douglas B.; "Stereoselective Alkene Isomerization over One Position [Erratum to document cited in CA157:133200]" J. Am. Chem. Soc., 2012, 134, 6400-6409. DOI: 10.1021/ja308091h
  31. Larsen, Casey R.; Grotjahn, Douglas B.; "Stereoselective Alkene Isomerization over One Position" J. Am. Chem. Soc., 2012, 134, 10357-10360. DOI: 10.1021/ja3036477
  32. Grotjahn, Douglas B.; Brown, Derek B.; Martin, Jessica K.; Marelius, David C.; Abadjian, Marie-Caline; Tran, Hai N.; Kalyuzhny, Gregory; Vecchio, Kenneth S.; Specht, Zephen G.; Cortes-Llamas, Sara A.; Miranda-Soto, Valentin; van Niekerk, Christoffel; Moore, Curtis E.; Rheingold, Arnold L.; "Evolution of Iridium-Based Molecular Catalysts during Water Oxidation with Ceric Ammonium Nitrate" J. Am. Chem. Soc., 2011, 133, 19024-19027. DOI: 10.1021/ja203095k
  33. Specht, Zephen G.; Cortes-Llamas, Sara A.; Tran, Hai N.; van Niekerk, Christoffel J.; Rancudo, Khing T.; Golen, James A.; Moore, Curtis E.; Rheingold, Arnold L.; Dwyer, Tammy J.; Grotjahn, Douglas B.; "Enabling bifunctionality and hemilability of N-heteroaryl NHC complexes" Chem. - Eur. J., 2011, 17, 19024-19027. DOI: 10.1002/chem.201100521
  34. Miranda-Soto, Valentin; Grotjahn, Douglas B.; Cooksy, Andrew L.; Golen, James A.; Moore, Curtis E.; Rheingold, Arnold L.; "A labile and catalytically active imidazol-2-yl fragment system" Angew. Chem., Int. Ed., 2011, 50, 19024-19027. DOI: 10.1002/anie.201005100
  35. Nair, Reji N.; Golen, James A.; Rheingold, Arnold L.; Grotjahn, Douglas B.; "Unexpected synthesis and structural characterization of Pt(II)Cl2-1,5-hexadiene from reaction of allyl chloride and K2PtCl4" Inorg. Chim. Acta, 2010, 364, 272-274. DOI: 10.1016/j.ica.2010.09.006
  36. Erdogan, Gulin; Grotjahn, Douglas B.; "Catalysis of Selective Hydrogen/Deuterium Exchange at Allylic Positions Using Deuterium Oxide" Top. Catal., 2010, 53, 1055-1058. DOI: 10.1007/s11244-010-9531-7
  37. Nair, Reji N.; Lee, Paul J.; Grotjahn, Douglas B.; "One-Pot Formation of Functionalized Indole and Benzofuran Derivatives Using a Single Bifunctional Ruthenium Catalyst" Top. Catal., 2010, 53, 1045-1047. DOI: 10.1007/s11244-010-9529-1
  38. Larsen, Casey R.; Grotjahn, Douglas B.; "New Insights on Kinetic Versus Thermodynamic Ratios in Catalyzed Alkene Isomerization" Top. Catal., 2010, 53, 1015-1018. DOI: 10.1007/s11244-010-9572-y
  39. Grotjahn, Douglas B.; "Structures, mechanisms, and results in bifunctional catalysis and related species involving proton transfer" Top. Catal., 2010, 53, 1009-1014. DOI: 10.1007/s11244-010-9571-z
  40. Grotjahn, Douglas B.; "Bifunctional organometallic catalysis and reactivity using heterocyclic phosphines and metalated heterocycles" Chem. Lett., 2010, 39, 908-914. DOI: 10.1246/cl.2010.908
  41. Grotjahn, Douglas B.; Kraus, John E.; Amouri, Hani; Rager, Marie-Noelle; Cooksy, Andrew L.; Arita, Amy J.; Cortes-Llamas, Sara A.; Mallari, Arthur A.; Di Pasquale, Antonio G.; Moore, Curtis E.; Liable-Sands, Louise M.; Golen, James D.; Zakharov, Lev N.; Rheingold, Arnold L.; "Multimodal Study of Secondary Interactions in Cp*Ir Complexes of Imidazolylphosphines Bearing an NH Group" J. Am. Chem. Soc., 2010, 132, 7919-7934. DOI: 10.1021/ja906712g
  42. Grotjahn, Douglas B.; "Heteroatoms moving protons: synthetic and mechanistic studies of bifunctional organometallic catalysis" Pure Appl. Chem., 2010, 82, 635-647. DOI: 10.1351/pac-con-09-10-31
  43. Nair, Reji N.; Lee, Paul J.; Rheingold, Arnold L.; Grotjahn, Douglas B.; "Single Bifunctional Ruthenium Catalyst for One-Pot Cyclization and Hydration giving Functionalized Indoles and Benzofurans" Chem. - Eur. J., 2010, 16, 635-647. DOI: 10.1002/chem.201001075
  44. Erdogan, Gulin; Grotjahn, Douglas B.; "Mild and Selective Deuteration and Isomerization of Alkenes by a Bifunctional Catalyst and Deuterium Oxide" J. Am. Chem. Soc., 2009, 131, 10354-10355. DOI: 10.1021/ja903519a
  45. Grotjahn, Douglas B.; Larsen, Casey; Erdogan, Gulin; Gustafson, Jeffery; Sharma, Abhinandini; Nair, Reji; "Bifunctional catalysis of alkene isomerization and its applications" Chem. Ind. (Boca Raton, FL, U. S.), 2009, 123, 379-387. DOI: 10.1021/ja903519a
  46. Grotjahn, Douglas B.; "Bifunctional catalysts and related complexes: structures and properties" Dalton Trans., 2008, 123, 6497-6508. DOI: 10.1039/b809274e
  47. Miranda-Soto, Valentin; Grotjahn, Douglas B.; DiPasquale, Antonio G.; Rheingold, Arnold L.; "Imidazol-2-yl Complexes of Cp*Ir as Bifunctional Ambident Reactants" J. Am. Chem. Soc., 2008, 130, 13200-13201. DOI: 10.1021/ja804713u
  48. Grotjahn, Douglas B.; Kragulj, Elijah J.; Zeinalipour-Yazdi, Constantinos D.; Miranda-Soto, Valentin; Lev, Daniel A.; Cooksy, Andrew L.; "Finding the Proton in a Key Intermediate of anti-Markovnikov Alkyne Hydration by a Bifunctional Catalyst" J. Am. Chem. Soc., 2008, 130, 10860-10861. DOI: 10.1021/ja803106z
  49. Grotjahn, Douglas B.; Zeng, Xi; Cooksy, Andrew L.; Kassel, W. Scott; DiPasquale, Antonio G.; Zakharov, Lev N.; Rheingold, Arnold L.; "Experimental and Computational Study of the Transformation of Terminal Alkynes to Vinylidene Ligands on trans-(Chloro)bis(phosphine)Rh Fragments and Effects of Phosphine Substituents. [Erratum to document cited in CA147:212016]" Organometallics, 2008, 27, 10860-10861. DOI: 10.1021/om8002569
  50. Grotjahn, Douglas B.; Miranda-Soto, Valentin; Kragulj, Elijah J.; Lev, Daniel A.; Erdogan, Guelin; Zeng, Xi; Cooksy, Andrew L.; "Hydrogen-Bond Acceptance of Bifunctional Ligands in an Alkyne-Metal π Complex" J. Am. Chem. Soc., 2008, 130, 20-21. DOI: 10.1021/ja0774616
  51. Kragulj, Elijah J.; Gustafson, Jeffery L.; Grotjahn, Douglas B.; "A convenient method for regeneration of free thiol from a tert-butyl thioether" Synlett, 2007, 130, 2851-2854. DOI: 10.1055/s-2007-991091
  52. Grotjahn, Douglas B.; Larsen, Casey R.; Gustafson, Jeffery L.; Nair, Reji; Sharma, Abhinandini; "Extensive Isomerization of Alkenes Using a Bifunctional Catalyst: An Alkene Zipper" J. Am. Chem. Soc., 2007, 129, 9592-9593. DOI: 10.1021/ja073457i
  53. Grotjahn, Douglas B.; Zeng, Xi; Cooksy, Andrew L.; Kassel, W. Scott; DiPasquale, Antonio G.; Zakharov, Lev. N.; Rheingold, Arnold L.; "Experimental and Computational Study of the Transformation of Terminal Alkynes to Vinylidene Ligands on trans-(Chloro)bis(phosphine)Rh Fragments and Effects of Phosphine Substituents" Organometallics, 2007, 26, 3385-3402. DOI: 10.1021/om700355r
  54. Grotjahn, Douglas B.; Gong, Yi; DiPasquale, Antonio G.; Zakharov, Lev N.; Rheingold, Arnold L.; "Bifunctional Imidazolylphosphine Ligands as Hydrogen Bond Donors Promote N-H and O-H Activation on Platinum" Organometallics, 2006, 25, 5693-5695. DOI: 10.1021/om060880b
  55. Grotjahn, Douglas B.; Zeng, Xi; Cooksy, Andrew L.; "Alkyne-to-Vinylidene Transformation on trans-(Cl)Rh(phosphine)2: Acceleration by a Heterocyclic Ligand and Absence of Bimolecular Mechanism" J. Am. Chem. Soc., 2006, 128, 2798-2799. DOI: 10.1021/ja058736p
  56. Grotjahn, Douglas B.; Gong, Yi; Zakharov, Lev; Golen, James A.; Rheingold, Arnold L.; "Changes in Coordination of Sterically Demanding Hybrid Imidazolylphosphine Ligands on Pd(0) and Pd(II)" J. Am. Chem. Soc., 2006, 128, 438-453. DOI: 10.1021/ja054779u
  57. Grotjahn, Douglas B.; "Bifunctional organometallic catalysts involving proton transfer or hydrogen bonding" Chem. - Eur. J., 2005, 11, 7146-7153. DOI: 10.1002/chem.200500253
  58. Lev, Daniel A.; Grotjahn, Douglas B.; Amouri, Hani; "Reversal of Reactivity in Diene-Complexed o-Quinone Methide Complexes: Insights and Explanations from ab Initio Density Functional Theory Calculations" Organometallics, 2005, 24, 4232-4240. DOI: 10.1021/om0504093
  59. Lev, Daniel A.; Grotjahn, Douglas B.; "An enzyme-like mechanism involving bifunctional Ru catalysts" Chem. Ind. (Boca Raton, FL, U. S.), 2005, 104, 237-241. DOI: 10.1021/om0504093
  60. Grotjahn, Douglas B.; Lev, Daniel A.; "Enzyme-like acceleration in catalytic anti-Markovnikov hydration of alkynes to aldehydes" Chem. Ind. (Boca Raton, FL, U. S.), 2005, 104, 227-236. DOI: 10.1021/om0504093
  61. Grotjahn, Douglas B.; Halfen, DeWayne T.; Ziurys, Lucy M.; Cooksy, Andrew L.; "Gas-Phase Synthesis, Submillimeter Spectra, and Precise Structure of Monomeric, Solvent-Free CuCH3" J. Am. Chem. Soc., 2004, 126, 12621-12627. DOI: 10.1021/ja0490166
  62. Grotjahn, Douglas B.; Lev, Daniel A.; "A general bifunctional catalyst for the anti-Markovnikov hydration of terminal alkynes to aldehydes gives enzyme-like rate and selectivity enhancements" J. Am. Chem. Soc., 2004, 126, 12232-12233. DOI: 10.1021/ja046360u
  63. Grotjahn, Douglas B.; Hoerter, Justin M.; Hubbard, John L.; "Double C-H Activation during Functionalization of Phenyl(methyl)ketene on Iridium(I) Using Alkynes. Synthesis of 1,4-Dien-3-ones" J. Am. Chem. Soc., 2004, 126, 8866-8867. DOI: 10.1021/ja048489+
  64. Grotjahn, Douglas B.; Joubran, Camil; "Oxidative addition of the C-O bond of amino acid esters to Rh(I) forming chelating acyl complexes" Inorg. Chim. Acta, 2004, 357, 3047-3056. DOI: 10.1016/j.ica.2004.05.028
  65. Grotjahn, Douglas B.; Van, Sang; Combs, David; Lev, Daniel A.; Schneider, Christian; Incarvito, Christopher D.; Lam, Kim-Chung; Rossi, Gene; Rheingold, Arnold L.; Rideout, Marc; Meyer, Christoph; Hernandez, Genaro; Mejorado, Lupe; "Substituent Control of Hydrogen Bonding in Palladium(II)-Pyrazole Complexes" Inorg. Chem., 2003, 42, 3347-3355. DOI: 10.1021/ic026104n
  66. Grotjahn, Douglas B.; Van, Sang; Combs, David; Lev, Daniel A.; Schneider, Christian; Rideout, Marc; Meyer, Christoph; Hernandez, Genaro; Mejorado, Lupe; "New Flexible Synthesis of Pyrazoles with Different, Functionalized Substituents at C3 and C5" J. Org. Chem., 2002, 67, 9200-9209. DOI: 10.1021/jo026083e
  67. Grotjahn, Douglas B.; Brewster, M. A.; Ziurys, Lucy M.; "The First Precise Molecular Structure of a Monomeric Transition Metal Cyanide, Copper(I) Cyanide" J. Am. Chem. Soc., 2002, 124, 5895-5901. DOI: 10.1021/ja0122492
  68. Grotjahn, Douglas B.; Incarvito, Christopher D.; Rheingold, Arnold L.; "Combined effects of metal and ligand capable of accepting a proton or hydrogen bond catalyze anti-Markovnikov hydration of terminal alkynes" Angew. Chem., Int. Ed., 2001, 40, 3884-3887. DOI: 10.1002/1521-3773(20011015)40:20<3884::aid-anie3884>3.0.co;2-7
  69. Grotjahn, Douglas B.; Collins, Laura S. B.; Wolpert, Marcus; Bikzhanova, Galina A.; Lo, H. Christine; Combs, David; Hubbard, John L.; "First Direct Structural Comparison of Complexes of the Same Metal Fragment to Ketenes in Both C,C- and C,O-Bonding Modes" J. Am. Chem. Soc., 2001, 123, 8260-8270. DOI: 10.1021/ja004324z
  70. Grotjahn, Douglas B.; Sheridan, P. M.; Jihad, I. Al; Ziurys, L. M.; "First Synthesis and Structural Determination of a Monomeric, Unsolvated Lithium Amide, LiNH2" J. Am. Chem. Soc., 2001, 123, 5489-5494. DOI: 10.1021/ja003422h
  71. Grotjahn, D. B.; Van, S.; Combs, D.; Kassel, W. S.; Rheingold, A. L.; "Hydrogen bonding in the crystal structure of bis{3-[(methylthio)methyl]pyrazole}copper(II) perchlorate" J. Inorg. Biochem., 2001, 85, 61-65. DOI: 10.1016/s0162-0134(00)00225-7
  72. Grotjahn, Douglas B.; Lo, H. Christine; Dinoso, Jason; Adkins, Charles D.; Li, Chunbang; Nolan, Steven P.; Hubbard, John L.; "Studies of the Synthesis and Thermochemistry of Coordinatively Unsaturated Chelate Complexes (η5-C5Me5)IrL2 (L2 = TsNCH2CH2NTs, TsNCH2CO2, CO2CO2)" Inorg. Chem., 2000, 39, 2493-2499. DOI: 10.1021/ic990870l
  73. Grotjahn, Douglas B.; Albers, Ronald J.; Beckman, Jacob; "Preparation of iminium salts from acetals" Synlett, 2000, 39, 633-634. DOI: 10.1055/s-2000-6630
  74. Grotjahn, Douglas B.; Bikzhanova, Galina A.; Collins, Laura S. B.; Concolino, Thomas; Lam, Kin-Chung; Rheingold, Arnold L.; "Controlled, Reversible Conversion of a Ketene Ligand to Carbene and CO Ligands on a Single Metal Center" J. Am. Chem. Soc., 2000, 122, 5222-5223. DOI: 10.1021/ja000243r
  75. Grotjahn, Douglas B.; Pesch, T. C.; Brewster, M. A.; Ziurys, L. M.; "Synthesis of CH3K in the Gas Phase: Structural and Mechanistic Trends for Monomeric, Unsolvated CH3M and HCCM (M = Li, Na, K)" J. Am. Chem. Soc., 2000, 122, 4735-4741. DOI: 10.1021/ja993136+
  76. Grotjahn, Douglas B.; Combs, David; Van, Sang; Aguirre, Gerardo; Ortega, Fernando; "Synthesis and Structure of Isomeric Palladium(II)-Pyrazole Chelate Complexes with and without an N-H Group as Hydrogen Bond Donor" Inorg. Chem., 2000, 39, 2080-2086. DOI: 10.1021/ic990995q
  77. Grotjahn, Douglas B.; Bikzhanova, Galina A.; Hubbard, John L.; "Phosphine Loss from Bis(phosphine)rhodium(I) η2-(C,O)-Diphenylketene Complexes Leading to η4-(C4) Coordination and Fluxionality of the Ketene" Organometallics, 1999, 18, 5614-5619. DOI: 10.1021/om990593q
  78. Grotjahn, Douglas B.; Joubran, Camil; Combs, David; "Controlled oxidative addition of amino acid esters to Rh(I)" J. Organomet. Chem., 1999, 589, 115-121. DOI: 10.1016/s0022-328x(99)00311-3
  79. Grotjahn, D. B.; "Arene-selective peptide and protein derivatization" Coord. Chem. Rev., 1999, 190-192, 1125-1141. DOI: 10.1016/s0010-8545(99)00161-7
  80. Grotjahn, Douglas B.; Joubran, Camil; Combs, David; Brune, Daniel C.; "High Arenophilicity and Water Tolerance in Direct Derivatization of Peptides and Proteins by Metal π-Coordination" J. Am. Chem. Soc., 1998, 120, 11814-11815. DOI: 10.1021/ja982602c
  81. Grotjahn, Douglas B.; Apponi, Aldo J.; Brewster, Matthew A.; Xin, Ju; Ziurys, Lucy M.; "Structures of solvent-free, monomeric LiCCH, NaCCH, KCCH" Angew. Chem., Int. Ed., 1998, 37, 2678-2681. DOI: 10.1002/(sici)1521-3773(19981016)37:19<2678::aid-anie2678>3.0.co;2-6
  82. Grotjahn, Douglas B.; Pesch, T. C.; Xin, J.; Ziurys, L. M.; "Structure of Solvent-Free, Monomeric CH3Li and CH3Na" J. Am. Chem. Soc., 1997, 119, 12368-12369. DOI: 10.1021/ja972613q

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